Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.
C. Obradors and A. M. Echavarren, Chem. Commun., 2014, 50, 16 DOI: 10.1039/C3CC45518A
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