Issue 3, 2014
From the journal:

Chemical Communications

Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase†

Min Wang,a   Feng Wang,*a   Jiping Ma,a   Mingrun Li,a   Zhe Zhang,a   Yehong Wang,a   Xiaochen Zhanga  and  Jie Xu*a  

* Corresponding authors

a Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P. R. China
E-mail: wangfeng@dicp.ac.cn, xujie@dicp.ac.cn
Web: www.fwang.dicp.ac.cn

Abstract

Gold nanoparticles supported on ceria{110} crystal planes were more reactive than on ceria{111} and {100} in the oxidative dehydrogenation of alcohols. Kinetic analysis and a Hammett plot suggest that hydride transfer is involved, and the cationic gold is catalytically active.

Graphical abstract: Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

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Article information

DOI
https://doi.org/10.1039/C3CC46180G
Article type
Communication
Submitted
13 Aug 2013
Accepted
28 Oct 2013
First published
28 Oct 2013

Chem. Commun., 2014,50, 292-294

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Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

M. Wang, F. Wang, J. Ma, M. Li, Z. Zhang, Y. Wang, X. Zhang and J. Xu, Chem. Commun., 2014, 50, 292 DOI: 10.1039/C3CC46180G

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