A series of water-soluble macro-initiators is synthesized to avoid radical loss in microfluidic on-chip photo cross-linking of hyaluronic acid methacrylate-containing water-in-oil emulsions. Their superior performance over known photo-initiators through the generation of water-soluble radicals and excellent biocompatibility are demonstrated.
Y. Ma, J. Thiele, L. Abdelmohsen, J. Xu and W. T. S. Huck, Chem. Commun., 2014, 50, 112 DOI: 10.1039/C3CC46733C
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