We present the observation that chloride serves as a simple catalyst for the acceleration of a self-assembly reaction between AsCl3 and dithiolate ligands (H2L) to form As2L3 assemblies. Studies on a model monomeric arsenic complex suggest that chloride may accelerate ligand exchange dynamics in pnictogen thiolates in general.
M. E. Carnes, M. S. Collins, N. R. Lindquist, E. Guzmán-Percástegui, M. D. Pluth and D. W. Johnson, Chem. Commun., 2014, 50, 73 DOI: 10.1039/C3CC47093H
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
