Highly selective defect-mediated photochemical CO2 conversion over fluorite ceria under ambient conditions

Dong Jiang; Wenzhong Wang; Erping Gao; Songmei Sun; Ling Zhang

doi:10.1039/C3CC47806H

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Highly selective defect-mediated photochemical CO₂ conversion over fluorite ceria under ambient conditions†

Dong Jiang,^a Wenzhong Wang,*^a Erping Gao,^a Songmei Sun^a and Ling Zhang^a

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* Corresponding authors

^a State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, PR China
E-mail: wzwang@mail.sic.ac.cn
Fax: +86 21 52413122

Abstract

A highly selective defect-mediated photochemical CO₂ conversion to CO over defective CeO₂ nanorods under ambient conditions (CO₂ 400 ppm) is presented. The local strain and surface oxygen vacancies embedded in the defect-rich CeO₂ are suggested to play a decisive role in mediating the photochemical CO₂ conversion.

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Article information

DOI: https://doi.org/10.1039/C3CC47806H
Article type: Communication
Submitted: 10 Oct 2013
Accepted: 31 Dec 2013
First published: 03 Jan 2014

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Chem. Commun., 2014,50, 2005-2007

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Highly selective defect-mediated photochemical CO₂ conversion over fluorite ceria under ambient conditions

D. Jiang, W. Wang, E. Gao, S. Sun and L. Zhang, Chem. Commun., 2014, 50, 2005 DOI: 10.1039/C3CC47806H

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