Mono-urea-functionalized pillar[5]arenes were prepared which exhibited abnormal urea behaviors. They were shown to form pseudo[1]rotaxanes with poor anion binding abilities in solution and [c2]daisy chains with an abnormal urea motif in the solid state.
![Graphical abstract: The self-complexation of mono-urea-functionalized pillar[5]arenes with abnormal urea behaviors](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC47823H&imageInfo.ImageIdentifier.Year=2014)
M. Ni, X. Hu, J. Jiang and L. Wang, Chem. Commun., 2014, 50, 1317 DOI: 10.1039/C3CC47823H
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