Di-isobutylaluminum hydride and tri-iso-butylaluminum (DIBAL 1, TIBAL 2) are shown to be efficient hydrogenation catalysts for a variety of imines at 100 °C and 100 atm of H2, operating via a hydroalumination/hydrogenolysis mechanism.
J. A. Hatnean, J. W. Thomson, P. A. Chase and D. W. Stephan, Chem. Commun., 2014, 50, 301 DOI: 10.1039/C3CC47889K
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