Issue 17, 2014
From the journal:

Chemical Communications

A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(iii) porphyrins†

Xi Chen,a   Shu-Qi Wu,a   Ai-Li Cuia  and  Hui-Zhong Kou*a  

* Corresponding authors

a Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
E-mail: kouhz@mail.tsinghua.edu.cn
Fax: +86 10 6277 1748
Tel: +86 10 6277 1748

Abstract

The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.

Graphical abstract: A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(iii) porphyrins

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Article information

DOI
https://doi.org/10.1039/C3CC48117D
Article type
Communication
Submitted
23 Oct 2013
Accepted
09 Dec 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 2120-2122

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A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins

X. Chen, S. Wu, A. Cui and H. Kou, Chem. Commun., 2014, 50, 2120 DOI: 10.1039/C3CC48117D

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