Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

Vincent Guillerm; Łukasz J. Weseliński; Mohamed Alkordi; M. Infas H. Mohideen; Youssef Belmabkhout; Amy J. Cairns; Mohamed Eddaoudi

doi:10.1039/C3CC48228F

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Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO₂ adsorption properties†

Vincent Guillerm,^a Łukasz J. Weseliński,^a Mohamed Alkordi,^a M. Infas H. Mohideen,^a Youssef Belmabkhout,^a Amy J. Cairns^a and Mohamed Eddaoudi*^a

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* Corresponding authors

^a Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
E-mail: mohamed.eddaoudi@kaust.edu.sa

Abstract

A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO₂ sorption properties.

This article is part of the themed collection: CO2 Separation, Capture and Reuse

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Article information

DOI: https://doi.org/10.1039/C3CC48228F
Article type: Communication
Submitted: 27 Oct 2013
Accepted: 26 Nov 2013
First published: 29 Nov 2013

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Chem. Commun., 2014,50, 1937-1940

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Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO₂ adsorption properties

V. Guillerm, Ł. J. Weseliński, M. Alkordi, M. I. H. Mohideen, Y. Belmabkhout, A. J. Cairns and M. Eddaoudi, Chem. Commun., 2014, 50, 1937 DOI: 10.1039/C3CC48228F

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Chemical Communications