Issue 18, 2014
From the journal:

Chemical Communications

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites†

Liangjun Li,ab   Sifu Tang,a   Chao Wang,ab   Xiaoxia Lv,ab   Min Jiang,a   Huaizhi Wua  and  Xuebo Zhao*a  

* Corresponding authors

a Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Shandong, China
E-mail: zhaoxb@qibebt.ac.cn
Fax: +86 0532-80662728

b University of Chinese Academy of Sciences, Beijing, China

Abstract

A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.

Graphical abstract: High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

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Article information

DOI
https://doi.org/10.1039/C3CC48275H
Article type
Communication
Submitted
29 Oct 2013
Accepted
10 Dec 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 2304-2307

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High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

L. Li, S. Tang, C. Wang, X. Lv, M. Jiang, H. Wu and X. Zhao, Chem. Commun., 2014, 50, 2304 DOI: 10.1039/C3CC48275H

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