Coexistence of cages and one-dimensional channels in a porous MOF with high H2 and CH4 uptakes

Jiandong Pang; Feilong Jiang; Mingyan Wu; Daqiang Yuan; Kang Zhou; Jinjie Qian; Kongzhao Su; Maochun Hong

doi:10.1039/C3CC48381A

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Coexistence of cages and one-dimensional channels in a porous MOF with high H₂ and CH₄ uptakes†

Jiandong Pang,^ab Feilong Jiang,^a Mingyan Wu,*^a Daqiang Yuan,^a Kang Zhou,^ab Jinjie Qian,^ab Kongzhao Su^ab and Maochun Hong*^a

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* Corresponding authors

^a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: wumy@fjirsm.ac.cn, hmc@fjirsm.ac.cn
Fax: +86-591-83794946
Tel: +86-591-83792460

^b University of the Chinese Academy of Sciences, Beijing, China

Abstract

A porous metal–organic framework with high surface area was designedly synthesized, in which polyhedral cages and one-dimensional channels coexist. It shows a total gravimetric H₂ uptake of 11.35 wt% at 77 K and 90 bar and a total CH₄ uptake of 305.07 cm³ g⁻¹ at 298 K and 35 bar.

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Article information

DOI: https://doi.org/10.1039/C3CC48381A
Article type: Communication
Submitted: 01 Nov 2013
Accepted: 09 Dec 2013
First published: 10 Dec 2013

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Chem. Commun., 2014,50, 2834-2836

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Coexistence of cages and one-dimensional channels in a porous MOF with high H₂ and CH₄ uptakes

J. Pang, F. Jiang, M. Wu, D. Yuan, K. Zhou, J. Qian, K. Su and M. Hong, Chem. Commun., 2014, 50, 2834 DOI: 10.1039/C3CC48381A

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Chemical Communications