Dimethyl carbamoyl tetrahydrocarbazoles undergo directed oxidation using standard conditions to exclusively provide products from C(sp3)–H oxidation. This result is in contrast to recent studies on the directed C–H olefination of hydrocarbazoles, which result in selective aromatic functionalisation.
![Graphical abstract: Palladium[ii] catalysed C(sp3)–H oxidation of dimethyl carbamoyl tetrahydrocarbazoles](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC48545E&imageInfo.ImageIdentifier.Year=2014)
Y. Nakano and D. W. Lupton, Chem. Commun., 2014, 50, 1757 DOI: 10.1039/C3CC48545E
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