Issue 16, 2014
From the journal:

Chemical Communications

Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation†

Pravas Deria,‡a   Wojciech Bury,‡ab   Joseph T. Hupp*a  and  Omar K. Farha*a  

* Corresponding authors

a Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail: j-hupp@northwestern.edu, o-farha@northwestern.edu

b Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland

Abstract

Solvent-assisted ligand incorporation (SALI) was utilized to efficiently insert various carboxylate-derived functionalities into the Zr-based metal–organic framework NU-1000 as charge compensating moieties strongly bound to the Zr6 nodes. SALI-derived functionalities are accessible for further chemical reactions such as click chemistry, imine condensation and pyridine quaternization.

Graphical abstract: Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation

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Article information

DOI
https://doi.org/10.1039/C3CC48562E
Article type
Communication
Submitted
08 Nov 2013
Accepted
16 Dec 2013
First published
09 Jan 2014

Chem. Commun., 2014,50, 1965-1968

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Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation

P. Deria, W. Bury, J. T. Hupp and O. K. Farha, Chem. Commun., 2014, 50, 1965 DOI: 10.1039/C3CC48562E

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