Issue 16, 2014
From the journal:

Chemical Communications

An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes†

O. Bortolini,*a   C. Chiappe,b   M. Fogagnolo,a   P. P. Giovannini,a   A. Massi,*a   C. S. Pomellib  and  D. Ragnoa  

* Corresponding authors

a Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Ferrara, Via Fossato di Mortara 17, 44121 Ferrara, Italy
E-mail: olga.bortolini@unife.it, alessandro.massi@unife.it
Fax: +39 0532240709
Tel: +39 0532455171

b Dipartimento di Farmacia, Università di Pisa, Via Bonanno 33, 56126 Pisa, Italy

Abstract

N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.

Graphical abstract: An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/C3CC48929A
Article type
Communication
Submitted
22 Nov 2013
Accepted
26 Dec 2013
First published
06 Jan 2014

Chem. Commun., 2014,50, 2008-2011

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An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes

O. Bortolini, C. Chiappe, M. Fogagnolo, P. P. Giovannini, A. Massi, C. S. Pomelli and D. Ragno, Chem. Commun., 2014, 50, 2008 DOI: 10.1039/C3CC48929A

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