We have synthesized and isolated two C2-symmetric enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern with the aid of an enantiopure cyclo-tris-malonate tether. An unexpected stereoisomerism was observed which was attributed to the spatial arrangement of spacers in the tether.
M. Riala and N. Chronakis, Chem. Commun., 2014, 50, 1995 DOI: 10.1039/C3CC48941H
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