Issue 17, 2014
From the journal:

Chemical Communications

An unsupported metal hydroxide for the design of molecular μ-oxo bridged heterobimetallic complexes†

A. J. Falzone,a   J. Nguyen,a   W. W. Weare,*a   R. D. Sommera  and  P. D. Boyleb  

* Corresponding authors

a Department of Chemistry, North Carolina State University, Campus Box 8204, Raleigh, NC, USA
E-mail: wwweare@ncsu.edu
Fax: +1-919-515-8920
Tel: +1-919-515-1746

b Department of Chemistry X-ray Facility, University of Western Ontario, 1151 Richmond Street North, London, ON, Canada
E-mail: pboyle@uwo.ca
Tel: +1-519-661-2111 ext. 82743

Abstract

A terminal and unsupported chromium(III) hydroxide is reported. The terminal hydroxide is used to synthesize the first example of a heterobimetallic Ti–O–Cr compound containing an unsupported μ-oxo bridge. The heterobimetallic complex exhibits a new absorbance at 288 nm (4.32 eV), which is assigned to a metal-to-metal charge transfer (MMCT) transition.

Graphical abstract: An unsupported metal hydroxide for the design of molecular μ-oxo bridged heterobimetallic complexes

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DOI
https://doi.org/10.1039/C3CC49066A
Article type
Communication
Submitted
27 Nov 2013
Accepted
23 Dec 2013
First published
24 Dec 2013

Chem. Commun., 2014,50, 2139-2141

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An unsupported metal hydroxide for the design of molecular μ-oxo bridged heterobimetallic complexes

A. J. Falzone, J. Nguyen, W. W. Weare, R. D. Sommer and P. D. Boyle, Chem. Commun., 2014, 50, 2139 DOI: 10.1039/C3CC49066A

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