Issue 22, 2014
From the journal:

Chemical Communications

Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule†

Abhishake Mondal,ab   Yanling Li,ab   Lise-Marie Chamoreau,ab   Mannan Seuleiman,ab   Lionel Rechignat,c   Azzedine Bousseksou,c   Marie-Laure Boillotd  and  Rodrigue Lescouëzec*ab  

* Corresponding authors

a Sorbonne Universités, UPMC Univ. Paris 06, UMR 8232, IPCM, F-75005, Paris, France
E-mail: rodrigue.lescouezec@upmc.fr
Fax: +33 (0)1 4427 3841
Tel: +33 (0)1 4427 3075

b CNRS, UMR 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France

c Laboratoire de Chimie de Coordination, CNRS UPR-8241, Route de Narbonne, 31077 Toulouse cedex 04, France

d Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR CNRS 8182, bât. 420, Université Paris-Sud 11, 11 rue George Clémenceau, 91405 Orsay cedex, France

Abstract

The self-assembly of [MoV(CN)8]3− and [FeII(bik)2(S)2]2+ affords a cyanide-bridged {MoV2FeII2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.

Graphical abstract: Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC49164A
Article type
Communication
Submitted
02 Dec 2013
Accepted
22 Jan 2014
First published
23 Jan 2014

Chem. Commun., 2014,50, 2893-2895

Author version available

Download author version (PDF)

Permissions

Request permissions

Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

A. Mondal, Y. Li, L. Chamoreau, M. Seuleiman, L. Rechignat, A. Bousseksou, M. Boillot and R. Lescouëzec, Chem. Commun., 2014, 50, 2893 DOI: 10.1039/C3CC49164A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements