Issue 35, 2014

Photocatalytic chemoselective reduction of epoxides to alkenes along with formation of ketones in alcoholic suspensions of silver-loaded titanium(iv) oxide at room temperature without the use of reducing gases

Abstract

(2,3-Epoxypropyl)benzene was chemoselectively reduced to allylbenzene along with formation of ketones in alcoholic suspensions of a silver-loaded titanium(IV) oxide photocatalyst at room temperature under atmospheric pressure without the use of reducing gases, and various epoxides were also reduced to the corresponding alkenes.

Graphical abstract: Photocatalytic chemoselective reduction of epoxides to alkenes along with formation of ketones in alcoholic suspensions of silver-loaded titanium(iv) oxide at room temperature without the use of reducing gases

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2013
Accepted
06 Mar 2014
First published
12 Mar 2014

Chem. Commun., 2014,50, 4558-4560

Author version available

Photocatalytic chemoselective reduction of epoxides to alkenes along with formation of ketones in alcoholic suspensions of silver-loaded titanium(IV) oxide at room temperature without the use of reducing gases

H. Kominami, S. Yamamoto, K. Imamura, A. Tanaka and K. Hashimoto, Chem. Commun., 2014, 50, 4558 DOI: 10.1039/C3CC49340G

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