Issue 17, 2014
From the journal:

Chemical Communications

From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis†

Simone Manzini,a   David J. Nelson,a   Tomas Lebl,a   Albert Poater,b   Luigi Cavallo,cd   Alexandra M. Z. Slawina  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK
E-mail: snolan@st-andrews.ac.uk

b Catalan Institute for Water Research (ICRA), Scientific and Technological Park of the University of Girona, H2O Building, Emili Grahit 101, E-17003 Girona, Spain

c Department of Chemistry and Biology, University of Salerno, Via Ponte don Melillo, Fisciano I-84084, Italy

d KAUST Catalyst Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia

Abstract

The synthesis and characterisation of [Ru(H)(η5-3-phenylindenyl)(iBu-Phoban)2] 4 is reported (iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (M10).

Graphical abstract: From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis

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Article information

DOI
https://doi.org/10.1039/C3CC49481K
Article type
Communication
Submitted
13 Dec 2013
Accepted
10 Jan 2014
First published
10 Jan 2014

Chem. Commun., 2014,50, 2205-2207

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From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis

S. Manzini, D. J. Nelson, T. Lebl, A. Poater, L. Cavallo, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2014, 50, 2205 DOI: 10.1039/C3CC49481K

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