A supramolecular Co(II)14-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

Suvendu Sekhar Mondal; Asamanjoy Bhunia; Alexandra Kelling; Uwe Schilde; Christoph Janiak; Hans-Jürgen Holdt

doi:10.1039/C3CC49698H

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A supramolecular Co(ii)₁₄-metal–organic cube in a hydrogen-bonded network and a Co(ii)–organic framework with a flexible methoxy substituent†

Suvendu Sekhar Mondal,^a Asamanjoy Bhunia,^b Alexandra Kelling,^a Uwe Schilde,^a Christoph Janiak^b and Hans-Jürgen Holdt*^a

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* Corresponding authors

^a Institut für Chemie, Anorganische Chemie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, 14476 Potsdam, Germany
E-mail: holdt@uni-potsdam.de
Fax: +49 331-977-5055
Tel: +39 331-977-5180

^b Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany

Abstract

The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO₃)₂·6H₂O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)₁₄-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

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Article information

DOI: https://doi.org/10.1039/C3CC49698H
Article type: Communication
Submitted: 22 Dec 2013
Accepted: 26 Mar 2014
First published: 26 Mar 2014
This article is Open Access

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Chem. Commun., 2014,50, 5441-5443

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A supramolecular Co(II)₁₄-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

S. S. Mondal, A. Bhunia, A. Kelling, U. Schilde, C. Janiak and H. Holdt, Chem. Commun., 2014, 50, 5441 DOI: 10.1039/C3CC49698H

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