Using polymeric ionic liquids and PEDOT as ion conducting separators and electrodes, respectively, an all-polymer-based organic electrochromic device (ECD) has been constructed. The advantages of such an ECD are: fast switching time (3 s), high coloration efficiency (390 cm2 C−1 at 620 nm), optical contrast up to ΔT = 22% and the possibility of working under vacuum.
A. S. Shaplov, D. O. Ponkratov, P. Aubert, E. I. Lozinskaya, C. Plesse, F. Vidal and Y. S. Vygodskii, Chem. Commun., 2014, 50, 3191 DOI: 10.1039/C3CC49876J
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