Issue 34, 2014
From the journal:

Chemical Communications

Branched tetrasilane substituted phosphines – synthesis and characterisation of PhSi(SiiPr2)3P and {PhSi(SiMe2)3}2P14†

Michael Feierabenda  and  Carsten von Hänisch*a  

* Corresponding authors

a Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW) of the Philipps-Universität Marburg, Hans-Meerwein-Straße, D-35032 Marburg, Germany
E-mail: haenisch@chemie.uni-marburg.de

Abstract

The branched trichlorotetrasilane PhSi(SiMe2Cl)3 reacts with P7(SiMe3)3 leading to formation of a new oligophosphane {PhSi(SiMe2)3}2P14 (1), which consists of two PhSi(SiMe2)3 substituted P7 norbornane units. The phosphatetrasila[1.1.1]pentane derivative PhSi(SiiPr2)3P (3) was obtained from the reaction of PhSi(SiiPr2Cl)3 (2) with Li3P.

Graphical abstract: Branched tetrasilane substituted phosphines – synthesis and characterisation of PhSi(SiiPr2)3P and {PhSi(SiMe2)3}2P14

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC00165F
Article type
Communication
Submitted
08 Jan 2014
Accepted
22 Feb 2014
First published
10 Mar 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 4416-4419

Author version available

Download author version (PDF)

Permissions

Request permissions

Branched tetrasilane substituted phosphines – synthesis and characterisation of PhSi(SiiPr2)3P and {PhSi(SiMe2)3}2P14

M. Feierabend and C. von Hänisch, Chem. Commun., 2014, 50, 4416 DOI: 10.1039/C4CC00165F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements