Issue 52, 2014
From the journal:

Chemical Communications

A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt–Ge bond rather than the Pt–Pt bond†

Makoto Tanabe,a   Kimiya Tanaka,a   Shumpei Ominea  and  Kohtaro Osakada*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, 4259-R1-3 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: kosakada@res.titech.ac.jp
Fax: +81-45-924-5224
Tel: +81-45-924-5224

Abstract

A new triangular triplatinum(0) complex with bridging diphenylgermylene ligands, [{Pt(PMe3)}3(μ-GePh2)3], undergoes insertion of ZC[triple bond, length as m-dash]CZ (Z = COOMe) into a Pt–Ge bond. The product contains a μ3-η2(∥)-CZ[double bond, length as m-dash]CZ-GePh2 ligand on the Pt3 plane. Two molecules of HC[triple bond, length as m-dash]CZ react to afford the Pt3 complex with chelating C, Ge- and Ge, Ge-ligands.

Graphical abstract: A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt–Ge bond rather than the Pt–Pt bond

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC00727A
Article type
Communication
Submitted
27 Jan 2014
Accepted
04 Mar 2014
First published
04 Mar 2014

Chem. Commun., 2014,50, 6839-6842

Author version available

Download author version (PDF)

Permissions

Request permissions

A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt–Ge bond rather than the Pt–Pt bond

M. Tanabe, K. Tanaka, S. Omine and K. Osakada, Chem. Commun., 2014, 50, 6839 DOI: 10.1039/C4CC00727A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements