Issue 38, 2014
From the journal:

Chemical Communications

A singlet ground state for a cobalt(ii)–anilinosalen radical complex†

Amélie Kochem,a   Gisèle Gellon,b   Olivier Jarjayes,b   Christian Philouze,b   Nicolas Leconte,b   Maurice van Gastel,a   Eckhard Billa  and  Fabrice Thomas*b  

* Corresponding authors

a Département de Chimie Moléculaire – Chimie Inorganique Redox Biomimétique (CIRE) – UMR CNRS 5250, Université J. Fourier, B. P. 53, 38041 Grenoble cedex 9, France
E-mail: Fabrice.Thomas@ujf-grenoble.fr
Fax: +33 476 514 836
Tel: +33 476 514 373

b Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany

Abstract

The cobalt(II) anilinosalen complex [CoII(L)] was prepared and subsequently oxidized by one electron. The resulting cation comprises a square planar low spin Co(II) ion anti-ferromagnetically exchange coupled to an anilinyl radical.

Graphical abstract: A singlet ground state for a cobalt(ii)–anilinosalen radical complex

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Article information

DOI
https://doi.org/10.1039/C4CC00952E
Article type
Communication
Submitted
05 Feb 2014
Accepted
21 Mar 2014
First published
24 Mar 2014

Chem. Commun., 2014,50, 4924-4926

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A singlet ground state for a cobalt(II)–anilinosalen radical complex

A. Kochem, G. Gellon, O. Jarjayes, C. Philouze, N. Leconte, M. van Gastel, E. Bill and F. Thomas, Chem. Commun., 2014, 50, 4924 DOI: 10.1039/C4CC00952E

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