Issue 29, 2014
From the journal:

Chemical Communications

Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer†

Y. Maximilian Klein,ab   Natasha F. Sciortino,a   Florence Ragon,a   Catherine E. Housecroft,b   Cameron J. Keperta  and  Suzanne M. Neville*a  

* Corresponding authors

a School of Chemistry, The University of Sydney, Sydney, NSW, 2006 Australia
E-mail: suzanne.neville@sydney.edu.au

b Department of Chemistry, University of Basel, Spitalstrasse 51, Switzerland

Abstract

The abrupt and hysteretic two-step spin crossover in a new triazole-based 2-D Hofmann-type complex shows a record breaking 120 K intermediate plateau (IP) region stabilized by negative cooperative interactions.

Graphical abstract: Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer

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Article information

DOI
https://doi.org/10.1039/C4CC01079E
Article type
Communication
Submitted
11 Feb 2014
Accepted
22 Feb 2014
First published
24 Feb 2014

Chem. Commun., 2014,50, 3838-3840

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Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer

Y. M. Klein, N. F. Sciortino, F. Ragon, C. E. Housecroft, C. J. Kepert and S. M. Neville, Chem. Commun., 2014, 50, 3838 DOI: 10.1039/C4CC01079E

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