The C24–C40 fragment of (−)-pulvomycin was prepared in enantiomerically pure form using a concise synthesis method (15 linear steps from D-fucose, 6.8% overall yield) featuring a diastereoselective addition to an aldehyde, a β-selective glycosylation and a Stille cross-coupling as the key steps.
S. Börding and T. Bach, Chem. Commun., 2014, 50, 4901 DOI: 10.1039/C4CC01338G
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