Issue 56, 2014
From the journal:

Chemical Communications

Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(iv) species with monoamido ligation: a putative reactive species generated from iron-bleomycin†

Yutaka Hitomi,*a   Kengo Arakawaa  and  Masahito Koderaa  

* Corresponding authors

a Department of Molecular Chemistry and Biochemistry, Doshisha University, 1-3 TataraMiyakodani, Kyotanabe, Kyoto 610-0321, Japan
E-mail: yhitomi@mail.doshisha.ac.jp

Abstract

The preparation and characterisation of an oxoiron(IV) species with monoamido ligation are described. Reactivity studies revealed the important role of the amido ligand in enhancing the ability of oxoiron(IV) complexes to promote hydrogen atom transfer from external alkanes.

Graphical abstract: Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(iv) species with monoamido ligation: a putative reactive species generated from iron-bleomycin

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Article information

DOI
https://doi.org/10.1039/C4CC01409J
Article type
Communication
Submitted
24 Feb 2014
Accepted
16 May 2014
First published
19 May 2014

Chem. Commun., 2014,50, 7485-7487

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Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(IV) species with monoamido ligation: a putative reactive species generated from iron-bleomycin

Y. Hitomi, K. Arakawa and M. Kodera, Chem. Commun., 2014, 50, 7485 DOI: 10.1039/C4CC01409J

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