Issue 51, 2014

Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

Abstract

A microporous metal–organic framework (mIm-MOF-14) has doubly interpenetrated anionic frameworks resulting from 2-methylimidazolate linking Zn(II) paddle-wheels of charge-neutral pto-type networks, and allows the inclusion of tetramethylammonium ion to exert an enhanced CO2 affinity.

Graphical abstract: Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2014
Accepted
10 May 2014
First published
12 May 2014

Chem. Commun., 2014,50, 6785-6788

Author version available

Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

N. Ko, K. Noh, S. Sung, H. J. Park, S. Y. Park and J. Kim, Chem. Commun., 2014, 50, 6785 DOI: 10.1039/C4CC01501K

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