Issue 50, 2014
From the journal:

Chemical Communications

Photocatalytic organic transformation by layered double hydroxides: highly efficient and selective oxidation of primary aromatic amines to their imines under ambient aerobic conditions†

Xiu-Jie Yang,a   Bin Chen,*b   Xu-Bing Li,b   Li-Qiang Zheng,*a   Li-Zhu Wu*b  and  Chen-Ho Tungab  

* Corresponding authors

a Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan, Shandong 250100, P. R. China
E-mail: lqzheng@sdu.edu.cn
Fax: +86-531-8856-4750
Tel: +86-531-8836-6062

b Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, The Chinese Academy of Science, Beijing 100190, P. R. China
E-mail: chenbin@mail.ipc.ac.cn, lzwu@mail.ipc.ac.cn
Fax: +86-10-8254-3580
Tel: +86-10-8254-3580

Abstract

We report the first application of layered double hydroxide as a photocatalyst in the transformation of primary aromatic amines to their corresponding imines with high efficiency and selectivity by using oxygen in an air atmosphere as a terminal oxidant under light irradiation.

Graphical abstract: Photocatalytic organic transformation by layered double hydroxides: highly efficient and selective oxidation of primary aromatic amines to their imines under ambient aerobic conditions

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Article information

DOI
https://doi.org/10.1039/C4CC01671H
Article type
Communication
Submitted
05 Mar 2014
Accepted
03 May 2014
First published
06 May 2014

Chem. Commun., 2014,50, 6664-6667

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Photocatalytic organic transformation by layered double hydroxides: highly efficient and selective oxidation of primary aromatic amines to their imines under ambient aerobic conditions

X. Yang, B. Chen, X. Li, L. Zheng, L. Wu and C. Tung, Chem. Commun., 2014, 50, 6664 DOI: 10.1039/C4CC01671H

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