Issue 92, 2014
From the journal:

Chemical Communications

High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide†

Huayan Yang,‡a   Yu Wang,‡a   Alison J. Edwards,b   Juanzhu Yana  and  Nanfeng Zheng*a  

* Corresponding authors

a State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen 361005, China
E-mail: nfzheng@xmu.edu.cn
Web: http://chem.xmu.edu.cn/groupweb/nfzheng/index.asp
Fax: +86 592 2183047
Tel: +86 592 2186821

b Bragg Institute, Australian Nuclear Science and Technology Organization, New Illawarra Road, Lucas Heights, New South Wales 2234, Australia

Abstract

A green gold-cluster, Au30S(StBu)18, was successfully prepared in high yield and crystallographically characterized. Each cluster consists of an Au22 core capped by a mixed layer of staple Au-thiolate units, bridging thiolates and a μ3-S2−.

Graphical abstract: High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide

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Article information

DOI
https://doi.org/10.1039/C4CC01773K
Article type
Communication
Submitted
09 Mar 2014
Accepted
24 Sep 2014
First published
24 Sep 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 14325-14327

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High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide

H. Yang, Y. Wang, A. J. Edwards, J. Yan and N. Zheng, Chem. Commun., 2014, 50, 14325 DOI: 10.1039/C4CC01773K

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