Issue 54, 2014

Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

Abstract

An aerobic oxidative cross-coupling reaction of alkenes with polyfluorobenzenes, through palladium-catalyzed allylic C–H activation, is reported. This attractive route provides a new way to forge allylic C–C bonds of valuable products, in good yields, with high regioselectivity.

Graphical abstract: Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

Supplementary files

Article information

Article type
Communication
Submitted
18 Mar 2014
Accepted
15 Apr 2014
First published
16 Apr 2014

Chem. Commun., 2014,50, 7202-7204

Author version available

Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

H. Jiang, W. Yang, H. Chen, J. Li and W. Wu, Chem. Commun., 2014, 50, 7202 DOI: 10.1039/C4CC02023E

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