A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

Min Ren; Song-Song Bao; Rute A. S. Ferreira; Li-Min Zheng; Luis D. Carlos

doi:10.1039/C4CC02085E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A layered erbium phosphonate in pseudo-D_5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation†

Min Ren,^a Song-Song Bao,^a Rute A. S. Ferreira,^b Li-Min Zheng*^a and Luis D. Carlos*^b

Author affiliations

* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
E-mail: lmzheng@nju.edu.cn

^b Physics Department, CICECO, University of Aveiro, Aveiro, Portugal
E-mail: lcarlos@ua.pt

Abstract

A layered erbium(III) phosphonate compound, [Er(notpH₄)(H₂O)]ClO₄·3H₂O (1), in which the Er^III ion has a pseudo-D_5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4CC02085E
Article type: Communication
Submitted: 20 Mar 2014
Accepted: 27 May 2014
First published: 30 May 2014

Download Citation

Chem. Commun., 2014,50, 7621-7624

Permissions

Request permissions

A layered erbium phosphonate in pseudo-D_5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

M. Ren, S. Bao, R. A. S. Ferreira, L. Zheng and L. D. Carlos, Chem. Commun., 2014, 50, 7621 DOI: 10.1039/C4CC02085E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications