We report a non-porous silver(I) coordinated phenanthroline-based polymer, which exhibits a high ideal ethylene/ethane adsorption selectivity (15/1) and high ethylene uptake (5.0 mmol gā1) at ambient temperature and pressure. Both silver(I) coordination and polymer structures are important for the high uptake of ethylene.
C. Yu, M. G. Cowan, R. D. Noble and W. Zhang, Chem. Commun., 2014, 50, 5745 DOI: 10.1039/C4CC02143F
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