A practical RhIII-catalyzed cascade olefination/annulation of picolinamides leading to pyrrolo[3,4-b]pyridines has been developed. The reaction shows wide scope, complete regiocontrol and excellent stereoselectivity.
![Graphical abstract: Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC02322F&imageInfo.ImageIdentifier.Year=2014)
Á. M. Martínez, N. Rodríguez, R. Gómez Arrayás and J. C. Carretero, Chem. Commun., 2014, 50, 6105 DOI: 10.1039/C4CC02322F
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