Issue 61, 2014
From the journal:

Chemical Communications

Bromide-bridged palladium(iii) chain complexes showing charge bistability near room temperature†

Shohei Kumagai,ab   Shinya Takaishi,*a   Brian K. Breedlove,a   Hiroshi Okamoto,c   Hisaaki Tanaka,d   Shin-ichi Kurodad  and  Masahiro Yamashita*abe  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
E-mail: yamasita@agnus.chem.tohoku.ac.jp
Tel: +81-22-795-6544

b WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

c Department of Advanced Material Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561, Japan

d Department of Applied Physics, Graduate School of Engineering, Nagoya University, Furocho, Chikusa-ku, Nagoya 464-8603, Japan

e CREST, JST, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Abstract

We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

Graphical abstract: Bromide-bridged palladium(iii) chain complexes showing charge bistability near room temperature

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC02547D
Article type
Communication
Submitted
07 Apr 2014
Accepted
05 Jun 2014
First published
19 Jun 2014

Chem. Commun., 2014,50, 8382-8384

Author version available

Download author version (PDF)

Permissions

Request permissions

Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

S. Kumagai, S. Takaishi, B. K. Breedlove, H. Okamoto, H. Tanaka, S. Kuroda and M. Yamashita, Chem. Commun., 2014, 50, 8382 DOI: 10.1039/C4CC02547D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements