Ni-catalysts are used for the first time to synthesize highly important α-hydroxy amides and β-amino alcohols from α-keto amides by chemoselective and complete reduction using hydrosilanes. Chemoselective complete reduction of α-keto amides in the presence of a simple amide group is a key benefit of these Ni-catalysts.
N. C. Mamillapalli and G. Sekar, Chem. Commun., 2014, 50, 7881 DOI: 10.1039/C4CC02744B
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