Allylbenzene derivatives are ubiquitous frameworks in organic chemistry. Herein is described an efficient copper-catalyzed cross-coupling reaction using vinylsilanes and benzyl bromides, leading to the synthesis of allylbenzenes. This methodology allows the use of cis, trans and 1,1′-disubstituted vinylsilanes as well as a large number of sensitive moieties.
L. Cornelissen, V. Cirriez, S. Vercruysse and O. Riant, Chem. Commun., 2014, 50, 8018 DOI: 10.1039/C4CC02923B
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