Here we report the synthesis of storable N-phenylcarbamate palladacycles that showed robust reactivity in the cross-coupling reaction with an alkyne-encoded protein with a second-order rate constant approaching 19 770 ± 930 M−1 s−1.
G. Cheng, R. K. V. Lim, C. P. Ramil and Q. Lin, Chem. Commun., 2014, 50, 11679 DOI: 10.1039/C4CC02969K
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