Kinetic resolution of racemic planar-chiral metallocenes was performed through the conjugate addition of a nucleophile to the enal part of substrates. While no enantiomeric discrimination was found with low-molecular-weight organocatalysts, a properly designed resin-supported peptide catalyzed the reaction in a highly selective manner.
M. Akiyama, K. Akagawa, H. Seino and K. Kudo, Chem. Commun., 2014, 50, 7893 DOI: 10.1039/C4CC03266G
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