Issue 59, 2014
From the journal:

Chemical Communications

Nickel-catalysed carboxylation of organoboronates†

Yusuke Makida,a   Enrico Marelli,a   Alexandra M. Z. Slawina  and  Steven P. Nolan*ab  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, UK
E-mail: snolan@st-andrews.ac.uk

b Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia

Abstract

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.

Graphical abstract: Nickel-catalysed carboxylation of organoboronates

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Article information

DOI
https://doi.org/10.1039/C4CC03650F
Article type
Communication
Submitted
14 May 2014
Accepted
05 Jun 2014
First published
05 Jun 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 8010-8013

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Nickel-catalysed carboxylation of organoboronates

Y. Makida, E. Marelli, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2014, 50, 8010 DOI: 10.1039/C4CC03650F

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