Photoelectronically active, metal organic framework films prepared by self-directed assembly of silanized porphyrin cobalt monomers†
Abstract
A novel and facile approach for preparing highly oriented porphyrin metal–organic framework films on various substrates is explored by employing self-directed assembly of silanized porphyrin cobalt monomers (SPCMs). The three-dimensional ordered porphyrin films display excellent photo-electronic performance.