Issue 67, 2014
From the journal:

Chemical Communications

Guest control of structure in porous organic cages†

Marc A. Little,a   Samantha Y. Chong,a   Marc Schmidtmann,a   Tom Hasella  and  Andrew I. Cooper*a  

* Corresponding authors

a Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool, UK
E-mail: aicooper@liv.ac.uk
Web: http://www.liv.ac.uk/cooper-group/

Abstract

Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconversions to be understood.

Graphical abstract: Guest control of structure in porous organic cages

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Article information

DOI
https://doi.org/10.1039/C4CC04158E
Article type
Communication
Submitted
30 May 2014
Accepted
25 Jun 2014
First published
10 Jul 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 9465-9468

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Guest control of structure in porous organic cages

M. A. Little, S. Y. Chong, M. Schmidtmann, T. Hasell and A. I. Cooper, Chem. Commun., 2014, 50, 9465 DOI: 10.1039/C4CC04158E

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