Issue 82, 2014
From the journal:

Chemical Communications

Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324†

Lidiya A. Maslovskaya,a   Andrei I. Savchenko,b   Elizabeth H. Krenske,b   Victoria A. Gordon,c   Paul W. Reddell,c   Carly J. Pierce,a   Peter G. Parsonsa  and  Craig M. Williams*b  

* Corresponding authors

a QIMR Berghofer Medical Research Institute, PO Royal Brisbane Hospital, Brisbane, Queensland, Australia

b School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, Queensland, Australia
E-mail: c.williams3@uq.edu.au

c EcoBiotics Limited, PO Box 1, Yungaburra, Queensland, Australia

Abstract

Investigation of Croton insularis afforded the first in class seco-casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family.

Graphical abstract: Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324

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Article information

DOI
https://doi.org/10.1039/C4CC05413J
Article type
Communication
Submitted
14 Jul 2014
Accepted
13 Aug 2014
First published
02 Sep 2014

Chem. Commun., 2014,50, 12315-12317

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Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324

L. A. Maslovskaya, A. I. Savchenko, E. H. Krenske, V. A. Gordon, P. W. Reddell, C. J. Pierce, P. G. Parsons and C. M. Williams, Chem. Commun., 2014, 50, 12315 DOI: 10.1039/C4CC05413J

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