Novel double-stranded polyacetylene with a perylene bisimide bridge has been efficiently synthesized by metathesis cyclopolymerization of bis(1,6-heptadiyne) derivatives, and exhibited good solubility, highly thermal and oxidative stability, low LUMO energy levels, narrow bandgaps, and regular ladder-like architecture.
W. Song, H. Han, J. Wu and M. Xie, Chem. Commun., 2014, 50, 12899 DOI: 10.1039/C4CC05524A
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