Copper(II)-catalyzed boronic acid promoted C–N bond cross-coupling reactions have been successfully developed for sequential N-arylation of C-amino-NH-azoles. These general protocols are compatible with a variety of aryl/hetero-aryl boronic acids and provided rapid access to a diverse array of diarylaminoazole derivatives in a two-step sequence or in one-pot.
D. Nageswar Rao, Sk. Rasheed, R. A. Vishwakarma and P. Das, Chem. Commun., 2014, 50, 12911 DOI: 10.1039/C4CC05628K
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