Issue 87, 2014
From the journal:

Chemical Communications

A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid†

Nga T. Nguyen,abc   Yuki Mori,bc   Takahiro Matsumoto,abc   Takeshi Yatabe,abc   Ryota Kabe,b   Hidetaka Nakai,ab   Ki-Seok Yoonac  and  Seiji Ogo*abc  

* Corresponding authors

a Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: ogo.seiji.872@m.kyushu-u.ac.jp
Fax: +81-92-802-2823
Tel: +81-92-802-2818

b Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

c International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

Graphical abstract: A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

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Article information

DOI
https://doi.org/10.1039/C4CC05911E
Article type
Communication
Submitted
30 Jul 2014
Accepted
09 Sep 2014
First published
19 Sep 2014

Chem. Commun., 2014,50, 13385-13387

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A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

N. T. Nguyen, Y. Mori, T. Matsumoto, T. Yatabe, R. Kabe, H. Nakai, K. Yoon and S. Ogo, Chem. Commun., 2014, 50, 13385 DOI: 10.1039/C4CC05911E

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