Issue 91, 2014

Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na

Abstract

A new radical oxytrifluoromethylation of alkenes via an aerobic Cvinyl–heteroatom bond oxygenation process is reported, in which O2 and a catalytic amount of K2S2O8 work in concert to activate CF3SO2Na. Mechanistic investigation disclosed that CF3SO2˙ could react with O2 to reinitiate radical chain process.

Graphical abstract: Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na

Supplementary files

Article information

Article type
Communication
Submitted
12 Aug 2014
Accepted
19 Sep 2014
First published
19 Sep 2014

Chem. Commun., 2014,50, 14101-14104

Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na

Q. Lu, C. Liu, Z. Huang, Y. Ma, J. Zhang and A. Lei, Chem. Commun., 2014, 50, 14101 DOI: 10.1039/C4CC06328G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements