Issue 87, 2014
From the journal:

Chemical Communications

A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor–acceptor interactions†

Tomoyuki Mochida,*a   Yusuke Funasako,ab   Kazuyuki Takahashi,a   Makoto Inokuchi,b   Takahiro Sakurai,c   Shohei Ikeda,d   Hitoshi Ohta,e   Hatsumi Morif  and  Mikio Uruichig  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, Rokkodai, Nada, Hyogo 657-8501, Japan
E-mail: tmochida@platinum.kobe-u.ac.jp
Fax: +81 78 803 5679
Tel: +81 78 803 5679

b Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Science, Yamaguchi, Onoda, Yamaguchi 756-0884, Japan

c Center for Supports to Research and Education Activities, Kobe University, Kobe, Hyogo 657-8501, Japan

d Department of Physics, Graduate School of Science, Kobe University, Kobe, Hyogo 657-8501, Japan

e Molecular Photoscience Research Center, Kobe University, Kobe, Hyogo 657-8501, Japan

f Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581, Japan

g Institute for Molecular Science, Myodaiji, Okazaki, Aichi 444-8585, Japan

Abstract

[Dineopentyl-biferrocene]2[Cl1TCNQ]7, which has an unprecedented high donor–acceptor ratio of 2 : 7, contains a linear paramagnetic hexamer of Cl1TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.

Graphical abstract: A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor–acceptor interactions

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Article information

DOI
https://doi.org/10.1039/C4CC06888B
Article type
Communication
Submitted
01 Sep 2014
Accepted
08 Sep 2014
First published
11 Sep 2014

Chem. Commun., 2014,50, 13370-13372

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A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor–acceptor interactions

T. Mochida, Y. Funasako, K. Takahashi, M. Inokuchi, T. Sakurai, S. Ikeda, H. Ohta, H. Mori and M. Uruichi, Chem. Commun., 2014, 50, 13370 DOI: 10.1039/C4CC06888B

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