Issue 8, 2014
From the journal:

Catalysis Science & Technology

Diastereo- and enantioselective reductive amination of cycloaliphatic ketones by preformed chiral palladium complexes†

Armando Cabrera,*a   Pankaj Sharma,a   F. Javier Pérez-Flores,a   Luis Velasco,a   J. Luis Ariasb  and  Laura Rubio-Pérez*a  

* Corresponding authors

a Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán 04510, México D.F.
E-mail: arcaor1@unam.mx, laurarpz@unam.mx
Tel: +52 55 56224400

b Facultad de Estudios Superiores Cuautitlán, Departamento de Química, UNAM, Cuautitlán Izcalli, Estado de México 54700, Mexico

Abstract

An efficient preformed chiral palladium catalyzed direct diastereo- and enantioselective reductive amination of un- and substituted cycloaliphatic ketones with primary aryl amines has been developed.

Graphical abstract: Diastereo- and enantioselective reductive amination of cycloaliphatic ketones by preformed chiral palladium complexes

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Article information

DOI
https://doi.org/10.1039/C4CY00058G
Article type
Paper
Submitted
15 Jan 2014
Accepted
07 Mar 2014
First published
14 Mar 2014

Catal. Sci. Technol., 2014,4, 2626-2630

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Diastereo- and enantioselective reductive amination of cycloaliphatic ketones by preformed chiral palladium complexes

A. Cabrera, P. Sharma, F. J. Pérez-Flores, L. Velasco, J. L. Arias and L. Rubio-Pérez, Catal. Sci. Technol., 2014, 4, 2626 DOI: 10.1039/C4CY00058G

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