Issue 11, 2014
From the journal:

Dalton Transactions

Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide†

Thomas Pugha  and  Richard A. Layfield*a  

* Corresponding authors

a School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: Richard.Layfield@manchester.ac.uk

Abstract

The three-coordinate iron(II) NHC complexes [(IPr)Fe(N′′)2] (1) and [(ItBu)Fe(N′′)2] (3) (N′′ = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(II) selenolates [(IPr)Fe(N′′)(SePh)] (6) and [ItBu(H)][(aItBu)Fe(SePh)3], [ItBu(H)][7], with complex 7 containing an abnormal NHC ligand.

Graphical abstract: Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

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Article information

DOI
https://doi.org/10.1039/C3DT53203H
Article type
Communication
Submitted
13 Nov 2013
Accepted
27 Nov 2013
First published
02 Dec 2013

Dalton Trans., 2014,43, 4251-4254

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Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

T. Pugh and R. A. Layfield, Dalton Trans., 2014, 43, 4251 DOI: 10.1039/C3DT53203H

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